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Colloid and Radionuclide
Retardation Experiment (CRR)
Experimental Approach
Introduction |
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Investigating colloid-mediated transport of repository safety-relevant
radionuclides under realistic, in situ conditions (including very
low radionuclide solubilities in the groundwater, radioprotection
constraints, analytical limitations etc) is a very complex task
and so it was decided to split the CRR project into two phases:
- Phase 1: feasibility phase including
literature studies,scoping laboratory and field experiments and
associated modelling efforts.
- Phase 2: the main field experiment
accompanied by supporting laboratory experiments and an intensive
modelling programme.
The results of Phase 1 showed that the in situ experiment would
certainly be feasible. The main results of this Phase may be summarised
as:
- Experiments simulating groundwater flow at the host-rock/bentonite
interface indicate that bentonite colloid generation can occur.
- Relatively high bentonite colloid concentrations have been shown
to remain stable in the alkaline groundwaters of the experimental
zone.
- Conversely, bentonite colloids are not stable within bentonite
porewater.
- In the cases of Am, Pu, Cs and U, the radionuclides examined
show a strong affinity for bentonite colloids, which may facilitate
migration of these radionuclides through a repository host rock.
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