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Hyperalkaline Plume in
Fractured Rock (HPF)
Introduction |
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HPF info sheet
(1870 kb)
ANDRA, France
JNC (now
JAEA), Japan
Nagra Switzerland
SKB
Sweden
POSIVA,
Finland |
In the case of low and intermediate level radioactive wastes (L/ILW)
and many chemo-toxic wastes, most current repository designs envisage
the use of large volumes of cementitious materials to immobilise
the waste and to backfill the repository.
The proportions of concrete/cement in a typical L & ILW repository
are shown below.


Although relative inventories are less, significant quantities
of structural concrete and cementitious grouts may be used in some
HLW / SF repository designs (see Waste
Disposal Overview). It has long been recognised that the use
of cementitous materials in an underground repository will lead
to the development of a "hyperalkaline plume" in the host
rock. This can be demonstrated by the following animation.
Cement pore waters are highly alkaline and cement leachates have
been predicted to interact with the repository rock. This could
significantly alter the original nature of the host formation, affecting
the retardation qualities by changing the original geochemical and
hydrological conditions. From a safety assessment point of view,
the extent of such an alteration zone (often called the "hyperalkaline
plume") and the influence on radionuclide retardation properties
of this altered far-field must be carefully assessed.
To date, information already exists, in the form of model predictions
based on laboratory and natural analogue studies (e.g. Maqarin in
Jordan - see www.natural-analogues.com),
on possible consequences of a hyperalkaline plume. The aim of HPF
is to combine this information with data from a realistic, medium-term
in-situ experiment which will characterise the development of such
a plume in a fractured rock.
The HPF (Hyperalkaline Plume in Fractured rock) project integrates
laboratory, modelling and natural analogue studies with the results
from the in-situ studies, to gain a better understanding of the
processes relevant to a cementitious nuclear waste repository.
Aims of the HPF experiment
- To assess the potential perturbations of a hyperalkaline plume
on a repository host rock under realistic, in-situ conditions.
- To provide a link between existing laboratory data (well constrained,
but short-term and unrealistic), natural analogue data (poorly
constrained, but long-term and realistic) and modelling data with
a medium term (up to four years), repository-relevant, in situ
experiment.
- To test coupled (geochemistry/transport) code predictions of
hyperalkaline plume interaction with fractured rocks, in particular
the role played by secondary minerals (cement phases, zeolites)
on potential fracture blocking and/or matrix clogging.
- To obtain a data set on time evolution of a coupled geochemical/hydraulic
system.
- To examine radionuclide uptake within the hyperalkaline plume
and compare this with available laboratory data on both a pristine
and altered far-field.
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